Atom transfer radical polymerization (ATRP): A versatile and forceful tool for functional membranes

The progress in atom transfer radical polymerization (ATRP) provides an effective means for the design and preparation of functional membranes. Polymeric membranes with different macromolecular architectures applied in fuel cells, including block and graft copolymers are conveniently prepared via ATRP. Moreover, ATRP has also been widely used to introduce functionality onto the membrane surface to enhance its use in specific applications, such as antifouling, stimuli-responsive, adsorption function and pervaporation. In this review, the recent design and synthesis of advanced functional membranes via the ATRP technique are discussed in detail and their especial advantages are highlighted by selected examples extract the principles for preparation or modification of membranes using the ATRP methodology.     

Polymer brush coatings for combating marine biofouling

A variety of functional polymer brushes and coatings have been developed for combating marine biofouling and biocorrosion with much less environmental impact than traditional biocides. This review summarizes recent developments in marine antifouling polymer brushes and coatings that are tethered to material surfaces and do not actively release biocides. Polymer brush coatings have been designed to inhibit molecular fouling, microfouling and macrofouling through incorporation or inclusion of multiple functionalities. Hydrophilic polymers, such as poly(ethylene glycol), hydrogels, zwitterionic polymers and polysaccharides, resist attachment of marine organisms effectively due to extensive hydration. Fouling release polymer coatings, based on fluoropolymers and poly(dimethylsiloxane) elastomers, minimize adhesion between marine organisms and material surfaces, leading to easy removal of biofoulants. Polycationic coatings are effective in reducing marine biofouling partly because of their good bactericidal properties. Recent advances in controlled radical polymerization and click chemistry have also allowed better molecular design and engineering of multifunctional brush coatings for improved antifouling efficacies.     

Belco脱硫塔的在线清洗

介绍了美国Belco公司脱硫塔在正常运行的情况下,通过一系列的数据分析,获取设备内部的结垢状况和结垢的部位,通过管道机器人,牵动柔性喷淋器,实现设备内部清洗流程的布置,进行清洗.     

用于氮氧化物处理的填料塔的设计

选用填料塔对草酸生产过程中产生的氮氧化物进行吸收处理。对填料塔本体进行了设计计算,结合已有的工程设计经验给出了确定填料塔本体尺寸的具体步骤,并讨论了设计应考虑的主要问题。所采用的工艺有效地降低了生产过程中氮氧化物的排放,降低了生产成本,减少了环境污染。     

甲醇双效精馏系统的优化研究

为优化焦炉气制甲醇工艺中甲醇双效精馏系统,利用流程模拟技术对系统进行模拟分析,对比分析模拟数据与实际数据,提出甲醇双效精馏系统的优化措施。结果表明:模拟数据与实际数据基本吻合,模拟状态下每天可产甲醇350.4 t,与实际产量350 t相符,说明Wilson方程可用于甲醇-水体系。甲醇双效精馏系统中所需蒸汽量为9.83 t/h,而实际工况中蒸汽使用量为12.2 t/h,实际工况中的蒸汽使用量仍偏大,应降低蒸汽使用量;加压精馏塔、常压精馏塔最佳回流比分别为1.50和0.94;加压精馏塔中第25块塔板为灵敏板,常压精馏塔中第18、38块塔板作为灵敏板,日常操作中应重点关注以上塔板温度的变化。     

SHELL气化洗涤塔出口合成气带水原因分析及对策

通过对洗涤塔内部结构的分析,阐述了洗涤塔出口合成气带水的现象及危害,找出引起洗涤塔工艺气带水的原因、带液后的处理措施,以及对洗涤塔减少带水的改造方向。     

“烟塔合一”内衬防腐技术的研究

结合采用“烟塔合一”排放技术的火力发电厂烟气腐蚀介质及腐蚀环境特点,对混凝土材质冷却塔内衬防腐蚀技术进行了比较,介绍了防腐蚀衬里或涂层对新钢筋混凝土设备基体表面的要求及对原有钢筋混凝土设备的影响,提出了冷却塔内防腐蚀方案为：采用厚膜型鳞片涂料,衬层厚度设计为1.2mm。     

无极绳绞车监控保护装置研究

为了实现轨道运输安全管理,解决斜巷运输中同时行车行人的问题,杜绝运输事故,绳绞车上安装监控系统的思路,研究制定技术方案,并介绍方案的各项功能。经过实际运行,该技术方案,并介绍方案的各项功能。可有效实现运输巷道中车辆和人员的监控,落实＂行车不行人,行人不行车＂的规定,煤矿轨道运输的管控由人防上升到技防,提升了轨道运输安全的信息化、智能化管控水平。     

稳定性ClO_2在电厂汽机循环冷却水处理中的应用

阐述了稳定性二氧化氯安全、高效、无毒的杀菌特性。通过其在鞍钢新钢铁齐大山铁矿热电分厂工业应用试验表明,稳定性二氧化氯杀菌剂基本不影响汽机循环冷却水pH值,杀菌率高,作用快,对汽机凝汽器铜管几乎无腐蚀作用,对膦系水质稳定剂无副作用,在电力行业的汽机循环冷却水处理中具有广阔的使用前景。     

低沸塔中设备法兰的合理设计

钢制化工容器强度计算规定中给出了设备法兰的当量计算压力公式,本文通过分析认为应该区别对待其中的长期载荷和短期载荷,这样在能保证安全的情况下减低制造成本,提高经济效益。